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- W156623297 abstract "This review deals mainly with various aspects of conformational analysis in saturated heterocyclic systems. The following topics are discussed: 1. Conformational equilibria in 2-aryl, 2-ethynyl and 2-vinyl-1, 3-dioxanes in various solvents. 2. The generalized anomeric effect in 1, 3-diazanes and its origin. 3. Unexpected conformational equilibria in 5-heterosubstituted 1, 3-dioxanes. 4. Normal and anomalous solvent effects in conformational equilibria of 1, 3-dioxanes with heteroatoms at C-5. Calculation of solvent effects. Correlation of δG° as a function of solvent with ET(30). A new scale of “solvent polarity”. 5. Interplay of hydrogen bonding with dipolar, non-bonded and eclipsing interactions in 5-hydroxymethyl-l, 3-dioxanes. 6. Highly stereoselective H-D exchanges in anancomeric 1, 3-dithianes. 7. Potential distortion of a cyclohexane or 1, 3-dioxane ring by a t- butyl substituent. Evidence from proton and 13C nmr and from X-ray structure analysis." @default.
- W156623297 created "2016-06-24" @default.
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- W156623297 date "1971-01-01" @default.
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- W156623297 title "ASPECTS OF CONFORMATIONAL ANALYSIS OF SMALL MOLECULES" @default.
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- W156623297 doi "https://doi.org/10.1016/b978-0-408-70321-5.50016-9" @default.
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