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- W1566264135 abstract "Abstract A detailed crystallochemical characterization of the (β)-phase found in BaO–In2O3–CuO ternary system at 930°C is presented. The phase originates from binary terminal Ba2In3O6.5 (Ba1.6In2.4)O5.2 and expands into the ternary system as a triangularly shaped domain, resulting from a double substitution of the (Ba1.6+mIn0.4−m)(In2−nCun)O5.2−(m+n)/2 type. The phase exhibits an already characterized crystal structure, known as the ‘doubled’ perovskite type, which was earlier ascribed to Ba2InCuO4.5 and to the series of Ba2In2−xCuxO5−Δ type solid solution. Based on a comparison of the experimental sample densities with those calculated for several models of possible distribution of the M-structure components it was shown that up to 50 at.% Ba, only oxygen deficiency persists in the crystal structure of the (β)-phase. However, on crossing the above mentioned concentration, an increasing number of vacancies appear in its (In+Cu) sublattice (the perovskite B-site), thus additionally increasing the overall structure deficiency. In spite of this, stability of the crystal structure increases." @default.
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- W1566264135 date "2000-06-01" @default.
- W1566264135 modified "2023-10-02" @default.
- W1566264135 title "Studies of BaO–In2O3–CuO ternary system" @default.
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- W1566264135 doi "https://doi.org/10.1016/s0925-8388(00)00725-8" @default.
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