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- W1566267518 abstract "The electronic spectra of a group of substituted arsines of general formula C6H5AsXY, where X, Y = C6H5, CH3, or CF3, were examined in the region 2100–3400 A. Two distinct band systems appeared which were characterized by their behavior under substitution and solvent effects. The first system, which appeared around 2700 A, was neither affected appreciably by changes in solvent polarity nor by the nature of X and Y. This system was attributed to the benzene π → π∗ transition. The second system was structureless and appeared as one strong band in the region of 2200–2500 A depending on the nature of X and Y. These bands were all blue shifted on changing the solvent from a hydrocarbon (cyclohexane) to a hydroxylic (methanol) or acid (acetic or trifluoroacetic) solvent. These were tentatively classified as charge transfer transitions involving an arsenic lone pair electron and a benzene ring. C6H5As(CF3)2 was the only substance which gave two such bands and an explanation of this was given which proposed an intramolecular FHC bridge in this molecule. The spectral assignments permitted some logical conclusions in regard to the relative electron withdrawing power of phenyl, methyl, and trifluoromethyl groups in the substituted arsines." @default.
- W1566267518 created "2016-06-24" @default.
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- W1566267518 date "1961-01-01" @default.
- W1566267518 modified "2023-09-24" @default.
- W1566267518 title "The electronic spectra of the arylarsines" @default.
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- W1566267518 doi "https://doi.org/10.1016/0022-2852(61)90076-5" @default.
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