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- W1566304714 abstract "A kinetic study of the oxidation of hexacyanoferrate(II) by peroxynitrite has been carried out, using a stopped-flow technique. The variation of the experimental rate constant over a wide concentration range of Fe(CN) 4 - 6 has been investigated under different experimental conditions in terms of pH, ionic strength and temperature. A correlation between k a x p and the substrate concentration has been obtained and this shows first-order behavior in substrate at high concentrations of Fe(CN) 4 - 6. A reaction mechanism is proposed, in which the hexacyanoferrate(II) reacts in competitive pathways with the peroxynitrous acid (direct oxidation) and with HO- and .NO 2 radicals formed in the homolysis of the peroxide bond of HOONO (indirect oxidation). Moreover, two individual constants, k c (the formation constant of the germinated radical pair [HO.NO 2 ]) and k 7 (direct oxidation constant), have been evaluated together with the thermodynamic parameters ofthese elementary steps." @default.
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- W1566304714 date "2004-01-01" @default.
- W1566304714 modified "2023-09-28" @default.
- W1566304714 title "Oxidation of Hexacyanoferrate(II) by Peroxynitrite. A Mechanistic and Kinetic Study" @default.
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