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- W1566330051 abstract "This chapter deals with the description of the free radical polymerization (FRP) mechanism including initiation, propagation, and bimolecular termination reaction steps. Additional reactions such as chain transfer are introduced to improve the process description. In FRP, the progress of the reaction is measured in terms of conversion of monomer into polymer. The random character of the events defining the length of each polymeric chain leads to a distribution of molecular weights (MWs) instead of a unique MW as in the case of small molecules. The full molecular weight distribution (MWD) can be obtained either by probabilistic arguments or by a kinetic approach. The chapter then discusses thermodynamics of polymerization, and controlled radical polymerization (CRP). The most popular and successful techniques for performing CRP are stable free radical (SFR) or nitroxide-mediated radical polymerization (NMRP), atom transfer radical polymerization (ATRP), and reversible addition-fragmentation transfer (RAFT) polymerization." @default.
- W1566330051 created "2016-06-24" @default.
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- W1566330051 date "2013-02-22" @default.
- W1566330051 modified "2023-10-16" @default.
- W1566330051 title "Free Radical Polymerization" @default.
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- W1566330051 doi "https://doi.org/10.1002/9781118480793.ch4" @default.
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