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- W1566583591 abstract "When naphthalene is carbonized in the presence of AlCl3, polymerization and disproportionation reactions mainly occur up to approximately 300°C. Then, when the temperature is further increased, the catalyst gives rise to additional processes which are accompanied by H2 evolution. Mesophase formation is observed at relatively low temperatures. After the catalyst removal the obtained mesophase seems to be stable in a wide temperature interval. Unusually low CH ratios and high aliphatic hydrogen contents were observed in the catalytically formed mesophase. These properties are probably responsible for the solubility behaviour in conventional solvents. It is thought that the polymerization and disproportionation processes referred to above lead to the formation of high molecular weight nearly planar molecules, which contain fully aromatic and tetralin-like rings in their structures. These molecules would then be able to enter into the stacking process leading to the mesophase formation." @default.
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- W1566583591 date "1981-01-01" @default.
- W1566583591 modified "2023-09-25" @default.
- W1566583591 title "Study of the AlCl3 catalytic activity on aromatic hydrocarbons—II" @default.
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- W1566583591 doi "https://doi.org/10.1016/0008-6223(81)90057-9" @default.
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