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- W1566606939 abstract "In iron mixed-valence complex, (n-C3H7)4N[FeIIFeIII(dto)3] (dto = C2O2S2), the linkage isomerisation and charge-transfer between FeII FeIII occur in the precipitation process. We succeeded the suppression of linkage-isomerization and charge-transfer in the formation process of (n-C3H7)4N[FeIIFeIII(dto)3] by the synthesis on low temperature condition and the selection of solvent. Moreover, we have found that the charge transfer occurs in the formation of (n-C4H9)4N[FeIIFeIII(mto)3] (mto = C2O3S) without linkage-isomerization." @default.
- W1566606939 created "2016-06-24" @default.
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- W1566606939 date "2010-03-01" @default.
- W1566606939 modified "2023-09-30" @default.
- W1566606939 title "Linkage-isomerization and charge-transfer in the formation of iron mixed valence complexes, (n-C3H7)4N[FeIIFeIII(dto)3] (dto = C2O2S2) and (n-C4H9)4N[FeIIFeIII(mto)3] (mto = C2O3S)" @default.
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- W1566606939 doi "https://doi.org/10.1088/1742-6596/217/1/012034" @default.
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