Matches in SemOpenAlex for { <https://semopenalex.org/work/W1566637070> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W1566637070 endingPage "59" @default.
- W1566637070 startingPage "41" @default.
- W1566637070 abstract "The structure of a dipolar fluid in contact with a solid is investigated using the optimized cluster theory. The solid-liquid interaction is described by an effective one-dimensional potential. The model of a perfect impenetrable wall is dropped. An adsorption potential similar to the non-electrostatic potential appearing in the classical models of the double layer is introduced. We show that the effect of a reasonable adsorption potential is localized in the first monolayer in contact with the solid although the total effect of the solid is non localized in this monolayer. No states of orientation predominate in such a way that we can justify a two- or three-state model. The potential drop gs(dip) across the interface and the change in the surface Gibbs energy due to the adsorption potential are calculated. An adsorption potential of magnitude 1kT gives gs(dip) - −0.6 V. In order to obtain the values of gs(dip) generally accepted in the literature, no dielectric constant or clusters should be introduced. Because of the competition between the dipolar interaction and the adsorption potential, an increase of the dipole moment does not necessarily increase gs(dip)." @default.
- W1566637070 created "2016-06-24" @default.
- W1566637070 creator A5004814392 @default.
- W1566637070 creator A5011431671 @default.
- W1566637070 creator A5034173614 @default.
- W1566637070 date "1985-03-01" @default.
- W1566637070 modified "2023-09-23" @default.
- W1566637070 title "Structure of a dipolar fluid in contact with a solid" @default.
- W1566637070 cites W1845618662 @default.
- W1566637070 cites W1990175766 @default.
- W1566637070 cites W1990813036 @default.
- W1566637070 cites W1993664574 @default.
- W1566637070 cites W1995007538 @default.
- W1566637070 cites W1997401765 @default.
- W1566637070 cites W2005594203 @default.
- W1566637070 cites W2007526063 @default.
- W1566637070 cites W2023573373 @default.
- W1566637070 cites W2027886127 @default.
- W1566637070 cites W2031605112 @default.
- W1566637070 cites W2031823734 @default.
- W1566637070 cites W2040405251 @default.
- W1566637070 cites W2044982952 @default.
- W1566637070 cites W2046179424 @default.
- W1566637070 cites W2050658212 @default.
- W1566637070 cites W2060677776 @default.
- W1566637070 cites W2062010676 @default.
- W1566637070 cites W2073191904 @default.
- W1566637070 cites W2077913273 @default.
- W1566637070 cites W2079628326 @default.
- W1566637070 cites W2080590224 @default.
- W1566637070 cites W2104043792 @default.
- W1566637070 cites W2108594125 @default.
- W1566637070 cites W2135941982 @default.
- W1566637070 doi "https://doi.org/10.1016/0368-1874(85)85513-1" @default.
- W1566637070 hasPublicationYear "1985" @default.
- W1566637070 type Work @default.
- W1566637070 sameAs 1566637070 @default.
- W1566637070 citedByCount "15" @default.
- W1566637070 crossrefType "journal-article" @default.
- W1566637070 hasAuthorship W1566637070A5004814392 @default.
- W1566637070 hasAuthorship W1566637070A5011431671 @default.
- W1566637070 hasAuthorship W1566637070A5034173614 @default.
- W1566637070 hasConcept C121332964 @default.
- W1566637070 hasConcept C147789679 @default.
- W1566637070 hasConcept C150394285 @default.
- W1566637070 hasConcept C159467904 @default.
- W1566637070 hasConcept C171250308 @default.
- W1566637070 hasConcept C173523689 @default.
- W1566637070 hasConcept C178790620 @default.
- W1566637070 hasConcept C179254644 @default.
- W1566637070 hasConcept C185592680 @default.
- W1566637070 hasConcept C192562407 @default.
- W1566637070 hasConcept C26873012 @default.
- W1566637070 hasConcept C2781345722 @default.
- W1566637070 hasConcept C2994054872 @default.
- W1566637070 hasConcept C41008148 @default.
- W1566637070 hasConcept C7070889 @default.
- W1566637070 hasConcept C74650414 @default.
- W1566637070 hasConcept C76155785 @default.
- W1566637070 hasConcept C97355855 @default.
- W1566637070 hasConceptScore W1566637070C121332964 @default.
- W1566637070 hasConceptScore W1566637070C147789679 @default.
- W1566637070 hasConceptScore W1566637070C150394285 @default.
- W1566637070 hasConceptScore W1566637070C159467904 @default.
- W1566637070 hasConceptScore W1566637070C171250308 @default.
- W1566637070 hasConceptScore W1566637070C173523689 @default.
- W1566637070 hasConceptScore W1566637070C178790620 @default.
- W1566637070 hasConceptScore W1566637070C179254644 @default.
- W1566637070 hasConceptScore W1566637070C185592680 @default.
- W1566637070 hasConceptScore W1566637070C192562407 @default.
- W1566637070 hasConceptScore W1566637070C26873012 @default.
- W1566637070 hasConceptScore W1566637070C2781345722 @default.
- W1566637070 hasConceptScore W1566637070C2994054872 @default.
- W1566637070 hasConceptScore W1566637070C41008148 @default.
- W1566637070 hasConceptScore W1566637070C7070889 @default.
- W1566637070 hasConceptScore W1566637070C74650414 @default.
- W1566637070 hasConceptScore W1566637070C76155785 @default.
- W1566637070 hasConceptScore W1566637070C97355855 @default.
- W1566637070 hasIssue "1" @default.
- W1566637070 hasLocation W15666370701 @default.
- W1566637070 hasOpenAccess W1566637070 @default.
- W1566637070 hasPrimaryLocation W15666370701 @default.
- W1566637070 hasRelatedWork W1922792838 @default.
- W1566637070 hasRelatedWork W1928337928 @default.
- W1566637070 hasRelatedWork W2026785565 @default.
- W1566637070 hasRelatedWork W2037021220 @default.
- W1566637070 hasRelatedWork W2038414511 @default.
- W1566637070 hasRelatedWork W2087010334 @default.
- W1566637070 hasRelatedWork W2099662887 @default.
- W1566637070 hasRelatedWork W3104552494 @default.
- W1566637070 hasRelatedWork W3136185807 @default.
- W1566637070 hasRelatedWork W4234720830 @default.
- W1566637070 hasVolume "184" @default.
- W1566637070 isParatext "false" @default.
- W1566637070 isRetracted "false" @default.
- W1566637070 magId "1566637070" @default.
- W1566637070 workType "article" @default.