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- W1566650743 abstract "Bismuth-layer–structured ferroelectric (BLSF) thin films with a composition of Bi3.25La0.75Ti3O12 were prepared by an acetic-acid–based sol-gel route. The ferroelectric, dielectric, and fatigue characteristics of the films over a wide temperature range from 300 K to 100 K were analyzed by using a computerized measurement system. The fatigue characteristic of the film was improved with decreasing temperature. This behavior is attributed to the temperature-dependent changes of domain movement (or freezing), diffusivity (or mobility) of charged defects, and their interactions. It was found that the onset of fatigue ( ∝ f/T) and the fatigue rate ( ∝ T) were temperature-dependent parameters. The activation energy of the fatigue rate in sol-gel–derived BLT films was about 1.07 eV, which coincides with that of oxygen vacancies in perovskite-type materials. We suggest that the fatigue mechanism in the BLT system is mainly due to the behavior (or movement) of oxygen vacancies." @default.
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- W1566650743 date "2006-10-01" @default.
- W1566650743 modified "2023-09-25" @default.
- W1566650743 title "Temperature-dependent fatigue rate in ferroelectric Bi 3.25 La 0.75 Ti 3 O 12 thin films" @default.
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- W1566650743 doi "https://doi.org/10.1209/epl/i2005-10604-2" @default.
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