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- W1566792959 abstract "Objectives of this one-year, Laboratory Directed Research and Development (LDRD) project were the expansion of fundamental knowledge of plutonium chemistry and the development of information for enhancing plutonium recovery methods and weapons safety. Results of kinetic studies demonstrate that the monoxide monohydride, PuO(H), formed during corrosion of plutonium by water in pyrophoric when dry and acts as an initiator for hydride-catalyzed reaction of the metal with air. The catalyzed corrosion rate of Pu is 10{sup 8} times faster than that in dry air and transforms plutonium into a readily aerosolized material. A potential application for the catalytic reaction is in the direct recovery of plutonium as oxide. Wet PuO(H) is non-pyrophoric and the safety hazard posed by its formation is reduced if the material is not allowed to dry." @default.
- W1566792959 created "2016-06-24" @default.
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- W1566792959 date "1997-10-01" @default.
- W1566792959 modified "2023-09-23" @default.
- W1566792959 title "Reaction kinetics relevant to the recycle hydride-dehydride process for plutonium recovery" @default.
- W1566792959 doi "https://doi.org/10.2172/532690" @default.
- W1566792959 hasPublicationYear "1997" @default.
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