Matches in SemOpenAlex for { <https://semopenalex.org/work/W1566862113> ?p ?o ?g. }
Showing items 1 to 59 of
59
with 100 items per page.
- W1566862113 endingPage "1805" @default.
- W1566862113 startingPage "1799" @default.
- W1566862113 abstract "Phenylmagnesium bromide reacted with 2-cyclohexylidenecyclohexanone (I) affording 2-(1-phenylcyclohexyl) cyclohexanone (II) in main, via 1, 4-addition. Besides, it accompanied 6-(1-phenylcyclohexyl)-6-oxo-hexanoic acid (III) as by-product, even though the reaction was carried out in a stream of nitrogen, using purified ether as a solvent. It was found that (a) III itself did not exist just after the Grignard reaction and appeared after heating of the reaction mixture at 70-80° ; (b) the ketone II, even in the enol form, did not produce a substance which convert into III by the absorption of oxygen. This suggested that the III-precursor, presumably a peroxide, was produced in the course of the Grignard reaction, thereafter transformed to III. Reactions for the identification of III and the Grignard reaction of other α, β-unsaturated ketones were persued." @default.
- W1566862113 created "2016-06-24" @default.
- W1566862113 creator A5020702248 @default.
- W1566862113 creator A5051226332 @default.
- W1566862113 date "1970-01-01" @default.
- W1566862113 modified "2023-10-07" @default.
- W1566862113 title "Grignard Reaction and Products. I. 1, 4-Addition of Arylmagnesium Bromide to 2-Alkylidenecyclohexanone and the Oxidative Cleavage therein" @default.
- W1566862113 doi "https://doi.org/10.1248/cpb.18.1799" @default.
- W1566862113 hasPublicationYear "1970" @default.
- W1566862113 type Work @default.
- W1566862113 sameAs 1566862113 @default.
- W1566862113 citedByCount "2" @default.
- W1566862113 crossrefType "journal-article" @default.
- W1566862113 hasAuthorship W1566862113A5020702248 @default.
- W1566862113 hasAuthorship W1566862113A5051226332 @default.
- W1566862113 hasBestOaLocation W15668621131 @default.
- W1566862113 hasConcept C155647269 @default.
- W1566862113 hasConcept C161790260 @default.
- W1566862113 hasConcept C178790620 @default.
- W1566862113 hasConcept C185592680 @default.
- W1566862113 hasConcept C2776300020 @default.
- W1566862113 hasConcept C2777495281 @default.
- W1566862113 hasConcept C2777738585 @default.
- W1566862113 hasConcept C2778380430 @default.
- W1566862113 hasConcept C2780450521 @default.
- W1566862113 hasConcept C2780616238 @default.
- W1566862113 hasConcept C40875361 @default.
- W1566862113 hasConceptScore W1566862113C155647269 @default.
- W1566862113 hasConceptScore W1566862113C161790260 @default.
- W1566862113 hasConceptScore W1566862113C178790620 @default.
- W1566862113 hasConceptScore W1566862113C185592680 @default.
- W1566862113 hasConceptScore W1566862113C2776300020 @default.
- W1566862113 hasConceptScore W1566862113C2777495281 @default.
- W1566862113 hasConceptScore W1566862113C2777738585 @default.
- W1566862113 hasConceptScore W1566862113C2778380430 @default.
- W1566862113 hasConceptScore W1566862113C2780450521 @default.
- W1566862113 hasConceptScore W1566862113C2780616238 @default.
- W1566862113 hasConceptScore W1566862113C40875361 @default.
- W1566862113 hasIssue "9" @default.
- W1566862113 hasLocation W15668621131 @default.
- W1566862113 hasOpenAccess W1566862113 @default.
- W1566862113 hasPrimaryLocation W15668621131 @default.
- W1566862113 hasRelatedWork W1971177380 @default.
- W1566862113 hasRelatedWork W2005270383 @default.
- W1566862113 hasRelatedWork W2053384754 @default.
- W1566862113 hasRelatedWork W2060804121 @default.
- W1566862113 hasRelatedWork W2064397104 @default.
- W1566862113 hasRelatedWork W2078436044 @default.
- W1566862113 hasRelatedWork W2079974723 @default.
- W1566862113 hasRelatedWork W2111814423 @default.
- W1566862113 hasRelatedWork W3027914011 @default.
- W1566862113 hasRelatedWork W4252880569 @default.
- W1566862113 hasVolume "18" @default.
- W1566862113 isParatext "false" @default.
- W1566862113 isRetracted "false" @default.
- W1566862113 magId "1566862113" @default.
- W1566862113 workType "article" @default.