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- W1566874837 abstract "We present experimentally derived potential curves and spin-orbit interaction functions for the strongly perturbed $A^{1}Sigma_{u}^{+}$ and $b^{3}Pi_{u}$ states of the cesium dimer. The results are based on data from several sources. Laser-induced fluorescence Fourier transform spectroscopy (LIF FTS) was used some time ago in the Laboratoire Aim'{e} Cotton primarily to study the $X ^{1}Sigma_{g}^{+}$ state. More recent work at Tsinghua University provides information from moderate resolution spectroscopy on the lowest levels of the $b^{3}Pi_{0u}^{pm}$ states as well as additional high resolution data. From Innsbruck University, we have precision data obtained with cold Cs$_{2}$ molecules. Recent data from Temple University was obtained using the optical-optical double resonance polarization spectroscopy technique, and finally, a group at the University of Latvia has added additional LIF FTS data. In the Hamiltonian matrix, we have used analytic potentials (the Expanded Morse Oscillator form) with both finite-difference (FD) coupled-channels and discrete variable representation (DVR) calculations of the term values. Fitted diagonal and off-diagonal spin-orbit functions are obtained and compared with {it ab initio} results from Temple and Moscow State universities." @default.
- W1566874837 created "2016-06-24" @default.
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- W1566874837 date "2011-03-28" @default.
- W1566874837 modified "2023-09-27" @default.
- W1566874837 title "Global analysis of data on the spin-orbit-coupled<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi>A</mml:mi></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msup><mml:mrow /><mml:mrow><mml:mn>1</mml:mn></mml:mrow></mml:msup><mml:msubsup><mml:mi>Σ</mml:mi><mml:mrow><mml:mi>u</mml:mi></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math>and<mml:math xmlns:mml=…" @default.
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