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• W1566881142 abstract "A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to monitor time-resolved infrared absorption of transient species produced upon irradiation at 248 nm of a flowing mixture of CH3SSCH3 and O2 at 260 K. Two transient bands observed with origins at 1397±1 and 1110±3 cm−1 are tentatively assigned to the antisymmetric CH3-deformation and OO stretching modes of syn-CH3SOO, respectively; the observed band contour indicates that the less stable anti-CH3SOO conformer likely contributes to these absorption bands. A band with an origin at 1071±1 cm−1, observed at a slightly later period, is assigned to the SO stretching mode of CH3SO, likely produced via secondary reactions of CH3SOO. These bands fit satisfactorily with vibrational wavenumbers and rotational contours simulated based on rotational parameters of syn-CH3SOO, anti-CH3SOO, and CH3SO predicted with density-functional theories B3LYP/aug-cc-pVTZ and B3P86/aug-cc-pVTZ. Two additional bands near 1170 and 1120 cm−1 observed at a later period are tentatively assigned to CH3S(O)OSCH3 and CH3S(O)S(O)CH3, respectively; both species are likely produced from self-reaction of CH3SOO. The production of SO2 via secondary reactions was also observed and possible reaction mechanism is discussed." @default.
• W1566881142 created "2016-06-24" @default.
• W1566881142 creator A5015444281 @default.
• W1566881142 creator A5057485693 @default.
• W1566881142 date "2010-11-09" @default.
• W1566881142 modified "2023-09-26" @default.
• W1566881142 title "Transient infrared spectra of CH3SOO and CH3SO observed with a step-scan Fourier-transform spectrometer" @default.
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• W1566881142 doi "https://doi.org/10.1063/1.3495765" @default.
• W1566881142 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21073219" @default.
• W1566881142 hasPublicationYear "2010" @default.
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