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- W1566885819 abstract "A combination of neutron total scattering measurement and reverse Monte Carlo (RMC) refinement is applied to the study of apical Cu-O bond distortions in the high-Tc superconductor YBa2Cu3O6.93. We show that the average structure is not consistent with a split-site model for the corresponding Cu and O positions, but that the local structure nevertheless reveals the existence of two separate apical Cu-O bond lengths. Using G(r) data obtained from a variety of Qmax values we show that this result is independent of the data treatment methodology. We also find that the resulting 'short' and 'long' Cu-O bond lengths agree well with the results of previous EXAFS studies. The existence of bimodal apical Cu-O bond distributions in the context of a single-site average structure model is interpreted in terms of correlated displacements of the Cu and O atoms. We find evidence also for the clustering of short apical Cu-O bonds within our RMC configurations." @default.
- W1566885819 created "2016-06-24" @default.
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- W1566885819 date "2011-12-21" @default.
- W1566885819 modified "2023-09-23" @default.
- W1566885819 title "Reverse Monte Carlo study of apical Cu-O bond distortions in YBa2Cu3O6.93" @default.
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- W1566885819 hasPublicationYear "2011" @default.
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