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- W1566995079 abstract "Abstract The two simplest mathematical models relating initial quasi-steady state rates and initial substrate concentrations are considered. In the classical model, plots of 1/r versus 1/S, S/r versus S, and r versus r/S are linear and therefore contain no curvature. In the next simplest model these plots may contain curvature. The curvature expected in r versus r/S plots is greater at any finite substrate concentration than the curvature expected in 1/r versus 1/S or S/r versus S plots constructed from the same data. Therefore, experimental data can best be examined for conformity to the classical model by plotting it in the r versus r/S form. Presentation of data in the 1/r versus 1/S or S/r versus S form is inferior in that it tends to obscure deviations from the classical model. The practicality of using r versus r/S plots rather than 1/r versus 1/S or S/r versus S plots is illustrated with data generated with random error from the model for which these plots are nonlinear. The r versus r/S plot is also found to be useful even when statistical calculations of significance levels are far below the 95% level usually desired for distinguishing models." @default.
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- W1566995079 date "1974-02-01" @default.
- W1566995079 modified "2023-09-30" @default.
- W1566995079 title "Graphical Procedures for the Detection of Deviations from the Classical Model of Enzyme Kinetics" @default.
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- W1566995079 doi "https://doi.org/10.1016/s0021-9258(19)42986-4" @default.
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