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- W1567108612 abstract "In this phase of the project, the mechanism of surface adsorption and enrichment of alkali on the potential additive particles is studied. Kaolinite is found to be a suitable sorbent for the removal of alkali during coal combustion. The kinetics and mechanism of adsorption of NaCl vapor on kaolinite were studied under both nitrogen and simulated flue gas (SFG) atmospheres. Under nitrogen, both chlorine and sodium were retained by the sorbent; however, under the simulated flue gas only sodium was retained. In both cases the adsorption was irreversible. High resolution scanning Auger analysis of kaolinite particles indicated the formation of a product layer during adsorption. Under the SFG atmosphere the product layer appears to be nephelite, a stable sodium aluminosilicate compound. The rate of adsorption dropped with the increase in alkali loading and a maximum saturation limit was observed. In the SFG environment this saturation capacity was approximately five times greater than that under the nitrogen atmosphere. An analytical model is presented which facilitates the extraction of fundamental kinetic information from experimental results. The model allows for surface adsorption as well as diffusion through both the saturated product layer and pores of the active sorbent." @default.
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- W1567108612 date "1988-02-01" @default.
- W1567108612 modified "2023-09-26" @default.
- W1567108612 title "Mechanism of surface enrichment and adhesion of coal combustion particulates: Fifth quarterly report" @default.
- W1567108612 hasPublicationYear "1988" @default.
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