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- W1567142479 abstract "Perturbed-hard-chain theory is extended to include chemical dimerization equilibria for strongly polar molecules. Using four adjustable molecular parameters, the extended theory gives good representation of the PVT properties of polar fluids, including water, alcohols and ketones. For nonpolar fluids only three adjustable parameters are required. Straightforward extension to mixtures requires one characteristic binary parameter for “physical” interactions and, for polar-polar mixtures, another for “chemical” interactions. The combined “physical and chemical” theory gives good representation for a variety of binary mixtures containing polar and/or nonpolar components. Particular attention is given to the systems methanol-water and ethanol-water where good results are obtained at pressures ranging from atmospheric to over 100 bars." @default.
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- W1567142479 date "1979-01-01" @default.
- W1567142479 modified "2023-10-04" @default.
- W1567142479 title "High-pressure vapor—liquid equilibria for mixtures containing one or more polar components" @default.
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- W1567142479 doi "https://doi.org/10.1016/0009-2509(79)85006-x" @default.
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