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- W1567182465 abstract "Crown Ethers from o-Quinone Diazides and Oxetane The carbenes 11, generated by photolysis of the di- and tetrachloro-o-quinone diazides 10, react with oxetane in a 1:3 ratio to give the 15-membered crown ethers 19. In the presence of methanol, the oxonium ions 12 are trapped with formation of 1-(aryloxy)-3-methoxypropanes (13). In the absence of additional nucleophiles, 12 reacts with oxetane until the chain length is appropriate for inverting intramolecular attack of the aryl oxide at the α-carbon atom of the oxonium ion (18 → 19)." @default.
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- W1567182465 date "1991-08-01" @default.
- W1567182465 modified "2023-10-17" @default.
- W1567182465 title "Notizen/Notes Kronenether aus <i>o</i> ‐Chinondiaziden und Oxetan" @default.
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- W1567182465 doi "https://doi.org/10.1002/cber.19911240825" @default.
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