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- W1567187648 abstract "We investigated the influence of ionic liquids (ILs) 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM]+[PF6]–, N-ethylpyridinium trifluoroacetate [EtPy]+[CF3COO]– and N-ethylpyridinium tetrafluoroborate [EtPy]+[BF4]– on uranium reduction by Clostridium sp. under anaerobic conditions. Potentiometric titration, UV-vis spectrophotometry, LC-MS and EXAFS analyses showed monodentate complexation between uranyl and BF4– PF6–; and bidentate complexation with CF3COO–. Ionic liquids affected the growth of Clostridium sp. as evidenced by decrease in optical density, changes in pH, gas production, and the extent of U(VI) reduction and precipitation of U(IV) from solution. Reduction of U(VI) to U(IV) was observed in the presence of [EtPy][BF4] and [BMIM][PF6] but not with [EtPy][CF3COO]." @default.
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- W1567187648 date "2011-01-01" @default.
- W1567187648 modified "2023-10-18" @default.
- W1567187648 title "Interactions of Ionic Liquids with Uranium and Its Bioreduction" @default.
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- W1567187648 doi "https://doi.org/10.1007/978-3-642-22122-4_53" @default.
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