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• W1567218161 abstract "Anionic silyl, germyl or stannyl complexes, [LnM-ER3]− (E = Si, Ge, Sn) exhibit a similar reactivity compared to di-anionic complexes [LnM]. However, there are several preparative advantages, because the steric and electronic properties of the ligands can be varied over a wide range, and often the stability of the complexes is rather high. Carbene complexes are formed upon reaction with geminal organic dihalides or cationic organic halides. With metal halides or halogeno complexes, ER3-substituted di- and trinuclear complexes are obtained. Selective cleavage of the M-E bond allows the deliberate increase of the nuclearity of polynuclear complexes." @default.
• W1567218161 created "2016-06-24" @default.
• W1567218161 creator A5075012306 @default.
• W1567218161 date "1993-11-25" @default.
• W1567218161 modified "2023-09-23" @default.
• W1567218161 title "Anionic Transition Metal Silyl Complexes: New Building Blocks in Coordination Chemistry" @default.
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• W1567218161 doi "https://doi.org/10.1002/9783527619931.ch46" @default.
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