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- W1567231619 abstract "Acetylenic compounds have been demonstrated to be of great synthetic potential in the preparation of functionalized sil(ox)anes by hydrosilylation reactions. Traditionally, organic compounds with olefinic unsaturation are reacted with hydrosil(ox)anes, which do not always simply add across the CC double bond. Side reactions with various other groups are common. On the other hand, a remarkable selectivity is encountered in the hydrosilylation of alkynes bearing other functional groups capable of reacting with Si-H groups. In competition with carbon-carbon triple bonds, however, their reactivity is cut down almost to zero and sil(ox)anes are cleanly derivatized with these functions. Alkenyl, acryloxyalkenyl, hydroxyalkenyl and diolic compounds are easily available by simple platinum catalyzed hydrosilylation, essentially without side reactions." @default.
- W1567231619 created "2016-06-24" @default.
- W1567231619 creator A5040790828 @default.
- W1567231619 date "2005-07-26" @default.
- W1567231619 modified "2023-10-03" @default.
- W1567231619 title "Regioselectivity in Hydrosilylation Reactions" @default.
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- W1567231619 doi "https://doi.org/10.1002/9783527620777.ch52" @default.
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