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- W1567259032 abstract "The interaction of tetraphenylhexapentaene with chlorotris(triphenylphosphine) rhodium produces a red complex in which rhodium is bound to the second CC bond of the cumulene. In contrast, reaction of the same cumulene with (PPh3)2Pt0 generated by reducing (PPh3)2PtCl2 with hydrazine in ethanol results in the formation of a yellow symmetrical complex as the kinetic product. This complex isomerizes to a red unsymmetrical complex. An X-ray crystal structure of bis(triphenylphosphine)chloro(tetraphenylhexapentaene)rhodium is reported." @default.
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- W1567259032 date "1990-09-01" @default.
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- W1567259032 title "Cumulenes as ligands" @default.
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- W1567259032 doi "https://doi.org/10.1016/0022-328x(90)85279-8" @default.
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