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- W1567301564 abstract "Abstract The kinetics of the non-catalytic thermal hydrocracking of Athabasca asphaltenes were studied over the temperature range 350–425 °C in a batch autoclave reactor. Gas, resins, oils (saturates + aromatics), coke and unreacted asphaltenes were separated. Product concentrations were determined as a function of reaction time for the above pseudoproducts. Two simple reaction models are proposed. In the first, the asphaltene fraction is considered to be a single reactant and the hydrocracking reaction a single irreversible reaction. The activation energy for asphaltene consumption was found to be 161 kJ mol −1 . In the second, more complex model, four pseudoproducts are used [asphaltenes, maltenes (oils + resins), coke and gas]. Activation energies for the reactions were found to be in the range 8–200 kJ mol −1 . Asphaltene hydrocracking reactions were found to have first-order kinetics. Experimental and calculated product distributions were in good agreement." @default.
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- W1567301564 date "1988-04-01" @default.
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- W1567301564 title "Non-catalytic hydrocracking of asphaltenes" @default.
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- W1567301564 doi "https://doi.org/10.1016/0016-2361(88)90349-3" @default.
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