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• W1567301688 abstract "Reversed-phase thin-layer chromatography with methanol-water as eluent was used to study relationships between retention and hydrophobicity of non-polar aromatic compounds. For polynuclear aromatic hydrocarbons, n-alkyl- and chloro-substituted benzenes, good correlation was observed between Rm values and log Poctanol. Significantly different correlations were obtained for polychlorinated biphenyls (PCBs) containing chlorine atoms in the positions ortho to the phenyl-phenyl bond. This effect could not be explained by the measured lower πoctanol values for ortho chlorine in PCBs. Estimation of hydrophobicity from aqueous solubility, S, combined with melting point data is restricted to S values higher than 1 μg/l. A group-contribution approach, including a retention index scale, will be very useful for correlation and prediction of reversed-phase retention, hydrophobicity and environmental and toxicological properties of chemicals." @default.
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• W1567301688 date "1982-04-01" @default.
• W1567301688 modified "2023-09-23" @default.
• W1567301688 title "Reversed-phase thin-layer chromatography of polynuclear aromatic hydrocarbons and chlorinated biphenyls" @default.
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• W1567301688 doi "https://doi.org/10.1016/s0021-9673(00)81319-9" @default.
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