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• W1567334628 abstract "Structural changes in $R{mathrm{MnO}}_{3}$ ($R=$ Y, Ho, Lu) under high pressure were examined by synchrotron x-ray diffraction methods at room temperature. Compression occurs more readily in the $mathit{ab}$ plane than along the $c$ axis. With increased pressure, a pressure-induced hexagonal to orthorhombic phase transition was observed starting at ensuremath{sim}22 GPa for Lu(Y)MnO${}_{3}$. When the pressure is increased to 35 GPa, a small volume fraction of Lu(Y)MnO${}_{3}$ is converted to the orthorhombic phase and the orthorhombic phase is maintained on pressure release. High-pressure infrared absorption spectroscopy and Mn $K$-edge near-edge x-ray absorption spectroscopy confirm that the hexagonal $P$${6}_{3}mathit{cm}$ structure is stable below ensuremath{sim}20 GPa and the environment around the Mn ion is not changed. Shifts in the unoccupied $p$-band density of states with pressure are observed in the Mn $K$-edge spectra. A schematic pressure-temperature phase diagram is given for the small ion $R{mathrm{MnO}}_{3}$ system." @default.
• W1567334628 created "2016-06-24" @default.
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• W1567334628 date "2011-06-27" @default.
• W1567334628 modified "2023-10-16" @default.
• W1567334628 title "High-pressure structural stability of multiferroic hexagonal<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi>R</mml:mi><mml:msub><mml:mi mathvariant=normal>MnO</mml:mi><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>(<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi>R</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant=normal>Y</mml:mi></mml:mrow></mml:math>, Ho, Lu)" @default.
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• W1567334628 doi "https://doi.org/10.1103/physrevb.83.224113" @default.
• W1567334628 hasPublicationYear "2011" @default.
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