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• W1567347346 abstract "The total synthesis of carbazomycin G (7) has been accomplished in six steps and 26 % overall yield starting from commercially available materials. As an efficient access to the tricyclic skeleton of carbazomycins A–H, an interesting thermal ring expansion/self-redox reaction cascade of intermediate 11 has been developed in our study. The self-redox reaction of intermediate 10 can be readily accelerated in the presence of triethylamine, and a plausible reaction mechanism for this process has been proposed. Finally, the synthesis of carbazomycin G was completed by the widely applied regioselective methylation reaction." @default.
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• W1567347346 date "2014-04-24" @default.
• W1567347346 modified "2023-09-24" @default.
• W1567347346 title "Total Synthesis of Carbazomycin G by a Thermal Ring Expansion/Self-Redox Reaction Cascade" @default.
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• W1567347346 doi "https://doi.org/10.1002/ejoc.201402065" @default.
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