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- W1567374805 abstract "Unlike endocyclic olefins the major product from the SeO2/H2O2 oxidation of exocyclic olefins is the same allylic alcohol as from the uncatalysed oxidation. Minor products derived from epoxide intermediates were investigated. The use of SeO2 as an allylic oxidant for olefins has been extensively investigated, the functionality of the product being to a degree solvent dependent. Although the earlier mechanism of Guillemonat2 is incorrect, his rules for the prediction of the position of oxidation still remain valid. A survey by Tratchenburg3 of the current position in SeO2 oxidation postulates allylic oxidation as proceeding through the intermediacy of an oxaselenocyclobutane to a selenite ester which is solvated by competitive unimolecular (SN1) and bimolecular (SN2′) processes (Scheme 1)." @default.
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- W1567374805 date "1976-01-01" @default.
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- W1567374805 title "Diterpene Chemistry—VI" @default.
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- W1567374805 doi "https://doi.org/10.1016/0040-4020(76)80026-9" @default.
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