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- W1567405384 abstract "The topochemical polymerization of the substituted diacetylene, 2,4-hexadiynylene bis(p-toluenesulfonate) (1), has been followed by X-ray crystallography and by determination of the elastic constants of polymerizing crystals. For the first time the crystal structure of a polymerizable diacetylene monomer has been solved and the coordinates of all atoms prior and after the reaction have been determined. The length of the growing polymer chains and their distribution in the monomer matrix can be determined by the evaluation of the Brillouin spectra in terms of a model which considers the polymerizing crystal as a composite material of high-modulus rod-like macromolecules dispersed in the low-modulus matrix of the residual monomer." @default.
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- W1567405384 date "1979-07-03" @default.
- W1567405384 modified "2023-10-03" @default.
- W1567405384 doi "https://doi.org/10.1002/macp.1979.021800716" @default.
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