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- W1567429654 abstract "Abstract The cation of an initiator, or some other salt, may participate in the complex equilibria with the monomer, the growth centre and particularly the lactam anion with which some cations form poorly dissociable lactamates. The Na + , Ba 2+ , Al 3+ at Cr 3+ lactamates were investigated; it was found that the bond strength between the cation and the lactam anion can be regarded as proportional to the electronegativity of the metal. The degrees of dissociation of some of these salts could be estimated from the courses of the activated and non-activated polymerizations. It follows from the polymerization results that, in the presence of cations more electronegative than aluminium, the anionic polymerization of caprolactam proceeds either very slowly or not at all." @default.
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- W1567429654 date "1972-09-01" @default.
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- W1567429654 title "Anionic polymerization of caprolactam—XLIV" @default.
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- W1567429654 doi "https://doi.org/10.1016/0014-3057(72)90002-x" @default.
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