FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1567459737> ?p ?o ?g. }

• W1567459737 endingPage "248" @default.
• W1567459737 startingPage "233" @default.
• W1567459737 abstract "Complete refinements of single-crystal X-ray diffraction intensity data for two tetragonal PrBa2Cu3O6 crystals and for two detwinned orthorhombic PrBa2Cu3O7 crystals, along with a more precise refinement for YBa2Cu3O6, have confirmed that the praseodymium compounds are strictly isostructural with the yttrium congeners. Crystallographic data available for the superconducting orthorhombic RBa2Cu3O7 analogs (R=Y, rare earth) were used to establish overall structural trends as a function of lanthanide size. In comparison with these trends, the present results obtained for orthorhombic PrBa2Cu3O7 indicate no markedly unusual structural features; the crystallographic behavior of Pr corresponds to that of the trivalent ion. However, subtle structural anomalies in the PrBa2Cu3Ox system were revealed by detailed comparisons of structural trends in RBa2Cu3Ox systems as a function of oxygen content. The axial CuO bond distance is unusually short in both PrBa2Cu3O6 and PrBa2Cu3O7, indicating stronger chemical linkage of the chains and planes as compared to the superconducting systems. Trends in the bond-valence sums and polyhedral volumes about R3+ suggest that in PrBa2Cu3O7 the increased spatial extension of the 4f-orbitals (as compared to neighboring Nd3+) mediates strong interactions with the CuO manifold that are capable of inhibiting superconductivity. The retention of superconductivity in Pr1.85Ce0.15CuO4 may arise from significant crystal-chemical differences between the T′ — and the YBa2Cu3O7-type structures: the T′ structure features (1) oxygen layers that are bonded only to Pr, not Cu, and (2) a larger R3+ polyhedral volume that results in greater isolation of the 4f-orbitals." @default.
• W1567459737 created "2016-06-24" @default.
• W1567459737 creator A5025939093 @default.
• W1567459737 creator A5060023762 @default.
• W1567459737 date "1992-10-01" @default.
• W1567459737 modified "2023-10-01" @default.
• W1567459737 title "In search of chemical clues" @default.
• W1567459737 cites W113162002 @default.
• W1567459737 cites W119910067 @default.
• W1567459737 cites W1522870691 @default.
• W1567459737 cites W1528719552 @default.
• W1567459737 cites W1549595992 @default.
• W1567459737 cites W1552301742 @default.
• W1567459737 cites W161255212 @default.
• W1567459737 cites W1635649390 @default.
• W1567459737 cites W1641505151 @default.
• W1567459737 cites W1975449206 @default.
• W1567459737 cites W1977726481 @default.
• W1567459737 cites W1978926039 @default.
• W1567459737 cites W1979652492 @default.
• W1567459737 cites W1980626500 @default.
• W1567459737 cites W1982117493 @default.
• W1567459737 cites W1983107282 @default.
• W1567459737 cites W1984807786 @default.
• W1567459737 cites W1986237379 @default.
• W1567459737 cites W1991675779 @default.
• W1567459737 cites W1995048904 @default.
• W1567459737 cites W1996835229 @default.
• W1567459737 cites W1999215800 @default.
• W1567459737 cites W2000671738 @default.
• W1567459737 cites W2001086881 @default.
• W1567459737 cites W2006569558 @default.
• W1567459737 cites W2007465284 @default.
• W1567459737 cites W2010644942 @default.
• W1567459737 cites W2016194710 @default.
• W1567459737 cites W2017998081 @default.
• W1567459737 cites W2023668467 @default.
• W1567459737 cites W2028349853 @default.
• W1567459737 cites W2032551484 @default.
• W1567459737 cites W2034043312 @default.
• W1567459737 cites W2034415091 @default.
• W1567459737 cites W2036460251 @default.
• W1567459737 cites W2037275759 @default.
• W1567459737 cites W2038564321 @default.
• W1567459737 cites W2041980599 @default.
• W1567459737 cites W2042420468 @default.
• W1567459737 cites W2042942553 @default.
• W1567459737 cites W2043241818 @default.
• W1567459737 cites W2043936314 @default.
• W1567459737 cites W2044101840 @default.
• W1567459737 cites W2053187220 @default.
• W1567459737 cites W2056572756 @default.
• W1567459737 cites W2061189027 @default.
• W1567459737 cites W2061276665 @default.
• W1567459737 cites W2067495089 @default.
• W1567459737 cites W2073798157 @default.
• W1567459737 cites W2074817895 @default.
• W1567459737 cites W2078279248 @default.
• W1567459737 cites W2078517173 @default.
• W1567459737 cites W2079208072 @default.
• W1567459737 cites W2081391780 @default.
• W1567459737 cites W2082215772 @default.
• W1567459737 cites W2084994089 @default.
• W1567459737 cites W2088039489 @default.
• W1567459737 cites W2088891125 @default.
• W1567459737 cites W2091002666 @default.
• W1567459737 cites W2091703749 @default.
• W1567459737 cites W2101741054 @default.
• W1567459737 cites W2104329537 @default.
• W1567459737 cites W2143571651 @default.
• W1567459737 cites W2167590372 @default.
• W1567459737 cites W2246680051 @default.
• W1567459737 cites W2286433148 @default.
• W1567459737 cites W2334200562 @default.
• W1567459737 cites W2394540757 @default.
• W1567459737 cites W2408629282 @default.
• W1567459737 cites W2587016857 @default.
• W1567459737 cites W2945121464 @default.
• W1567459737 cites W2951810930 @default.
• W1567459737 cites W308196853 @default.
• W1567459737 cites W41972865 @default.
• W1567459737 cites W4232106003 @default.
• W1567459737 doi "https://doi.org/10.1016/0921-4534(92)90469-s" @default.
• W1567459737 hasPublicationYear "1992" @default.
• W1567459737 type Work @default.
• W1567459737 sameAs 1567459737 @default.
• W1567459737 citedByCount "47" @default.
• W1567459737 countsByYear W15674597372020 @default.
• W1567459737 crossrefType "journal-article" @default.
• W1567459737 hasAuthorship W1567459737A5025939093 @default.
• W1567459737 hasAuthorship W1567459737A5060023762 @default.
• W1567459737 hasConcept C115624301 @default.
• W1567459737 hasConcept C121332964 @default.
• W1567459737 hasConcept C145148216 @default.
• W1567459737 hasConcept C147120987 @default.
• W1567459737 hasConcept C155860418 @default.
• W1567459737 hasConcept C168900304 @default.
• W1567459737 hasConcept C170751736 @default.

• next