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- W1567507319 abstract "This thesis describes attempts to develop new technically clean radical cyclisation technologies. The work focuses on novel radical oxidation processes, whereby selective hydrogen-atom abstraction forms carbon-centred radicals able to undergo intermolecular radical additions, or cyclisation to form 5- 6-membered rings. A new and unreported cyclisation pathway has been identified, albeit a low yielding pathway. This novel N-halosuccinimide cyclisation technology constructs cyclic architectures of med-chem importance and crucially without the requirement for tin or other toxic metals. Particularly noteworthy was the use of N-iodosuccinimide to promote cyclisation of dihydro-isoindol-1-one derivatives." @default.
- W1567507319 created "2016-06-24" @default.
- W1567507319 creator A5089965001 @default.
- W1567507319 date "2013-06-01" @default.
- W1567507319 modified "2023-09-27" @default.
- W1567507319 title "RADICAL ENDEAVOURS: THE PURSUIT OF NOVEL RADICAL CYCLISATION TECHNOLOGIES" @default.
- W1567507319 hasPublicationYear "2013" @default.
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