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- W1567674237 abstract "Isomerization of the molecular ion precedes alkyl radical elimination from many primary aliphatic amines. Rearrangement of the carbon skeleton is initiated by 1,5-hydrogen abstraction by the -NH2+· and converts primary-alkyl amines to sec- and tert-alkyl amines; fragmentation is then by α-cleavage of the rearranged molecular ions. Isomerization is also encountered for amines branched at the α-carbon atom. The elimination of propene from n-pentylamine and of a butenyl radical from neo-pentylamine is discussed. Remote (δ or ε) cleavage does not contribute to the low-energy reactions." @default.
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- W1567674237 date "1983-02-01" @default.
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- W1567674237 title "Slow alkyl, alkene, and alkenyl loss from primary alkylamines" @default.
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- W1567674237 doi "https://doi.org/10.1016/0020-7381(83)87206-4" @default.
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