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- W1567693522 abstract "In situ X-ray absorption near edge structure (XANES) investigations were carried out at chlorine K edge and palladium L 3 edge to study the mechanism of the thermal decomposition of ammonium hexachloropalladate. The spectra show a characteristic feature for the initial step that might be explained as the formation of the precursor via ligand exchange (Cl ⇒ NH 3 ). Multiple scattering calculations (Feff 8) for the Cl K , Pd and Rh L 3 edges were successful in simulating the XANES spectra of the precursor as well as the reference compounds (NH 4 ) 2 [PdCl 4 ] and (NH 4 ) 3 [RhCl 6 ]." @default.
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- W1567693522 date "2001-03-01" @default.
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- W1567693522 title "Thermal decomposition of (NH<sub>4</sub>)<sub>2</sub>[PdCl<sub>6</sub>] studied by <i>in situ</i> X-ray absorption spectroscopy" @default.
- W1567693522 doi "https://doi.org/10.1107/s0909049500015958" @default.
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