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- W1567700315 abstract "By means of the following solid oxide galvanic cells: MnO + Nd 2 O 3 + NdMnO 3 |O -2 |Ni + NiO and Mn 3 O 4 + NdMnO 3 + NdMn 2 O 5 |O -2 | air the equilibrium oxygen pressure was determined for the reactions: 2MnO+ Nd 2 O 3 + 1/2O 2 = 2NdMnO 3 and Mn 3 O 4 + 3NdMnO 3 +O 2 = 3NdMn 2 O 5 . From the determined equilibrium oxygen partial pressure the corresponding G i b b s free energy change for these reactions was derived in the form: ΔG 0 f,NdMO3 = -267241+ 90.34 . T (J) and ΔG 0 f,NdMn2O5 = -326957 + 223.0 . T (J) Finally, conditions of phase equilibria for the Nd-Mn-O system at fixed pressure and temperature were suggested." @default.
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- W1567700315 date "2002-01-01" @default.
- W1567700315 modified "2023-09-24" @default.
- W1567700315 title "Thermodynamics of NdMnO3 and NdMn2O5 phases determined by the E.M.F. method" @default.
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