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- W1567751864 abstract "The optimization of retention in liquid-solid chromatography (LSC) is explored in the present paper. Previously it was shown possible to calculate solvent strength (ε0 values) for multi-component mobile phases, and specifically for quaternary solvent mixtures ABCD. With ε0 held optimum and constant for a particular sample, the composition of ABCD can be further varied for optimization of separation factors α (solvent selectivity) for various solute-pairs in the sample of interest. The selection of optimum pure solvents AD for this purpose and the systematic variation in the proportions of these solvents for optimum separation are approached here in terms of a fundamental description of how solvent selectivity arises in LSC. In this paper we discuss two major contributions to solvent selectivity: solvent/solute localization and solvent-specific localization. In a later paper we apply these findings for the development of a systematic approach to the optimization of retention in LSC separation." @default.
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- W1567751864 date "1981-11-01" @default.
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- W1567751864 title "Theoretical basis for systematic optimization of mobile phase selectivity in liquid-solid chromatography" @default.
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- W1567751864 doi "https://doi.org/10.1016/s0021-9673(00)82062-2" @default.
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