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- W1567772017 abstract "The reaction of Li{2,6-(NEt2CH2)2C6H3} with BCl3 · Et2O in hexane yields BCl2[2-{BCl3(NEt2CH2)}-6-(NEt2CH2)C6H3] (1) as the thermodynamically favoured product. If BCl3 · pyridine is employed, only Cl{2,6-(NEt2CH2)2C6H3} is formed. 1 reacts with [PPh4]Cl to give the BCl3-free product BCl2{2,6-(NEt2CH2)2C6H3} (2) with formation of [PPh4][BCl4]. Li{2-(NMe2CH2)C6H4} reacts with BCl3 to give BCl2{2-NMe2CH2)C6H4} (3). 1–3 were characterized spectroscopically (NMR, IR, MS) and their crystal structures were determined: 1, T = 260(2) K, triclinic, P1, with a = 7.069(2) A, b = 10.837(5) A, c = 14.090(5) A, α = 90.09(2), β = 104.16(2), γ = 97.35(2), V = 1037.3(7) A3, Z = 2, d(calcd) = 1.429 g cm−3, 3409 independent reflections, and R1 = 0.0460, wR2 = 0.0889 (for reflections with I > 2σ(I)), R1 = 0.0752, wR2 = 0.1082 (all data); 2, T = 213(2) K, monoclinic, P21/c, with a = 13.1797(9) A, b = 7.5833(5) A, c = 18.6796(13) A, β = 108.974(1), V = 1765.5(2) A3, Z = 4, d(calcd) = 1.238 g cm−3, 3174 independent reflections, ..." @default.
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- W1567772017 date "1997-10-01" @default.
- W1567772017 modified "2023-10-18" @default.
- W1567772017 title "Synthesis and Molecular Structures of the Base-stabilized Arylboron Dichlorides BCl<sub>2</sub>{2,6-(NEt<sub>2</sub>CH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>} and BCl<sub>2</sub>{2-(NMe<sub>2</sub>CH<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>}" @default.
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- W1567772017 doi "https://doi.org/10.1080/10241229712331341274" @default.
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