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- W1567784010 abstract "In NMR spectroscopy, one measures the chemical shift of a particular peak in a spectrum with respect to a reference compound whose chemical shift is set to a particular arbitrary value for convenience. The NMR chemical shift is not a fundamental quantity, but is a derived quantity defined in terms of the nuclear magnetic shielding. To connect the chemical shift scales and chemical shift values used in NMR spectroscopy with fundamental molecular and electronic properties, one must establish an absolute shielding scale, whereby the absolute nuclear magnetic shielding for a particular compound (a reference compound) is measured. An absolute shielding scale allows one to make use of quantum chemical calculations of shielding tensors because a proper comparison between experimental chemical shift tensors and calculated nuclear magnetic shielding tensors may be made." @default.
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- W1567784010 date "2011-03-15" @default.
- W1567784010 modified "2023-10-14" @default.
- W1567784010 title "Chemical Shift Scales on an Absolute Basis" @default.
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- W1567784010 doi "https://doi.org/10.1002/9780470034590.emrstm0072.pub2" @default.
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