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- W1567787888 abstract "Spinel lithium manganese oxides LiMn1.6M0.4O4 (M=Mn, Co, Cr, Ni) for the cathode materials of the lithium ion secondary batteries were studied by electron energy loss spectroscopy (EELS). The ELNES spectra at Mn L- and O K-edge of the extracted lithium or substituted to Mn 16d site with third cations were successfully obtained. Electrochemically deintercalated Li1−xMn2O4 showed a chemical shift of both Mn L- and O K-edges to the higher energy side compared with those of the stoichiometric LiMn2O4 indicating oxidation of Mn and O due to the electrochemical deintercalation of Li. Substitution of M for Mn (M=Co, Cr, Ni) also caused a similar spectral shift of Mn L- and O K-edges. These shifts suggest lowering of the energy levels of the inner atomic orbitals compared with that of LiMn2O4." @default.
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- W1567787888 date "2001-07-01" @default.
- W1567787888 modified "2023-09-26" @default.
- W1567787888 title "EELS analysis of electrochemically deintercalated Li1−xMn2O4 and substituted spinels LiMn1.6M0.4O4 (M = Co, Cr, Ni)" @default.
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- W1567787888 doi "https://doi.org/10.1016/s0378-7753(01)00693-0" @default.
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