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- W1567872216 abstract "In alkaline solutions reduction of pyruvic acid occurs in two waves (IA1 and IA2) separated by 0.2-0.3 V. The more positive wave (IA1) corresponds to the reduction of an ion pair {CH3COCOO− Me+}, the more negative wave (IA2) to that of the anion CH3COCOO−. The height of IA1 depends on the equilibrium concentration of the ion pair and on the rate of its formation. From the dependence of IA1 on [Me+] it is possible to obtain the product kfK (where kf is the rate constant of ion-pair formation, K = [ion pair]/[Me−][CH3COCOO−]). The reactivity of the cation increases in the sequence Li+ < Na+ < K+ < Cs+. Tetra-n-butylammonium ion acts as a surfactant; tetramethylammonium ion forms the ion pair but also shows surface activity." @default.
- W1567872216 created "2016-06-24" @default.
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- W1567872216 date "1988-03-01" @default.
- W1567872216 modified "2023-09-27" @default.
- W1567872216 title "Ion-pair formation in aqueous solutions of pyruvate anions" @default.
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- W1567872216 doi "https://doi.org/10.1016/0022-0728(88)87118-3" @default.
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