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- W1567971510 abstract "When an aqueous solution containing mercury (II), thiopyrine and eosine was shaken with 1, 2-dichloroethane at pH 10, an ion pair formed from cationic mercury (II)-thiopyrine complex and anionic eosine was extracted into the organic phase. Based on this reaction, a sensitive extraction-spectrophotometric determination method for trace of mercury was established by the absorbance measurement at 540 nm. This method is applicable to the determination of mercury less than 2.5 μg/ml. Various common cations and anions except for silver (I) and iodide did not interfere the determination practically. Molar ratio of mercury (II) to thiopyrine and eosine was found to be 1 : 2 : 1 by the continuous variation method." @default.
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- W1567971510 date "1978-01-01" @default.
- W1567971510 modified "2023-09-27" @default.
- W1567971510 title "Thiopyrazolone derivatives as analytical reagents. XVI. Extraction-spectrophotometric determination of trace of mercury by ternary complex formed from mercury(II) and thiopyrine in the presence of eosine." @default.
- W1567971510 doi "https://doi.org/10.1248/cpb.26.3139" @default.
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