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- W1567989368 abstract "Abstract Recent results are presented illustrating principal mechanistic differences between alkane isomerization in liquid acids and over solid acids, including bifunctional catalysts. Isotopic labeling shows that butane isomerization over solid acids proceeds preferentially as a bimolecular process, i.e. via a C 8 intermediate, which subsequently decomposes, preferentially into two iso -C 4 structures. Bronsted acid sites in zeolites form chemical bonds with metal clusters. The resulting metal-proton adducts function as “collapsed bifunctional sites”." @default.
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- W1567989368 date "1998-01-01" @default.
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- W1567989368 title "Catalytic isomerization over metal, acid and hybridsites" @default.
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- W1567989368 doi "https://doi.org/10.1016/s0167-2991(98)80274-7" @default.
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