FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1569015762> ?p ?o ?g. }

• W1569015762 endingPage "2556" @default.
• W1569015762 startingPage "2545" @default.
• W1569015762 abstract "The reaction kinetics of 2-thiophenesulphonyl chloride with anion and neutral nucleophiles was studied in H2O, D2O and in protic solvents-H2O (10% vv) and aprotic solvents-H2O (10% vv) mixtures at 25°. Analysing the rate constants measured in water by Bronsted, Ritchie and Edwards equations the conclusion drawn that, for the nucleophilic order against the sulphonyl sulphur, basicity is of prime importance, although there may well be some dependence on polarizability and solvation. Solvent isotope effects show that the reactions occur by nucleophilic catalysis rather than by a general base mechanism. Water is the solvent in which there is the greater reactivity than in either protic solvents or aprotic-protic mixtures. By solubility measurements and applying Parker's equation the contributions of solvation energies of both reactants and transition states to the free energy of activation are calculated. Solvent effects on nucleophilic reactivities are discussed in terms of S parameters (similar to Ritchie N+ parameters), and by the approach of multiparameter empirical correlations. The data point out that solvation plays a large role on nucleophilic order. A complete comprehension of the problem would require an equation that takes into some account solvent effects. The homogeneous comparison of 2-thiophenesulphonyl chloride data with those of α-disulphone, p-anisyl p-methoxybenzenesulphinyl sulphone and benzenesulphonyl chloride shows that the same factors are involved in driving the nucleophilic reactivity for these compounds." @default.
• W1569015762 created "2016-06-24" @default.
• W1569015762 creator A5017951005 @default.
• W1569015762 creator A5057025801 @default.
• W1569015762 creator A5079517551 @default.
• W1569015762 date "1978-01-01" @default.
• W1569015762 modified "2023-10-16" @default.
• W1569015762 title "Reactions of 2-thiophenesulphonyl chloride with anion and neutral nucleophiles" @default.
• W1569015762 cites W1140101468 @default.
• W1569015762 cites W1502600908 @default.
• W1569015762 cites W1965237114 @default.
• W1569015762 cites W1970999824 @default.
• W1569015762 cites W1971812208 @default.
• W1569015762 cites W1973074429 @default.
• W1569015762 cites W1979904985 @default.
• W1569015762 cites W1982704548 @default.
• W1569015762 cites W1983530002 @default.
• W1569015762 cites W2020317651 @default.
• W1569015762 cites W2023208947 @default.
• W1569015762 cites W2023544416 @default.
• W1569015762 cites W2027727419 @default.
• W1569015762 cites W2032466609 @default.
• W1569015762 cites W2039190858 @default.
• W1569015762 cites W2056040984 @default.
• W1569015762 cites W2060834383 @default.
• W1569015762 cites W2069009149 @default.
• W1569015762 cites W2072922607 @default.
• W1569015762 cites W2077510656 @default.
• W1569015762 cites W2078359622 @default.
• W1569015762 cites W2082231254 @default.
• W1569015762 cites W2091220668 @default.
• W1569015762 cites W2092969761 @default.
• W1569015762 cites W2320140611 @default.
• W1569015762 cites W2322902045 @default.
• W1569015762 cites W2331000569 @default.
• W1569015762 cites W2332254228 @default.
• W1569015762 cites W2334206913 @default.
• W1569015762 cites W2952448382 @default.
• W1569015762 cites W3005062799 @default.
• W1569015762 doi "https://doi.org/10.1016/0040-4020(78)88385-9" @default.
• W1569015762 hasPublicationYear "1978" @default.
• W1569015762 type Work @default.
• W1569015762 sameAs 1569015762 @default.
• W1569015762 citedByCount "4" @default.
• W1569015762 countsByYear W15690157622021 @default.
• W1569015762 crossrefType "journal-article" @default.
• W1569015762 hasAuthorship W1569015762A5017951005 @default.
• W1569015762 hasAuthorship W1569015762A5057025801 @default.
• W1569015762 hasAuthorship W1569015762A5079517551 @default.
• W1569015762 hasConcept C121332964 @default.
• W1569015762 hasConcept C132439834 @default.
• W1569015762 hasConcept C142724271 @default.
• W1569015762 hasConcept C147597530 @default.
• W1569015762 hasConcept C148093993 @default.
• W1569015762 hasConcept C148898269 @default.
• W1569015762 hasConcept C155574463 @default.
• W1569015762 hasConcept C155647269 @default.
• W1569015762 hasConcept C161790260 @default.
• W1569015762 hasConcept C178790620 @default.
• W1569015762 hasConcept C178907741 @default.
• W1569015762 hasConcept C179104552 @default.
• W1569015762 hasConcept C185592680 @default.
• W1569015762 hasConcept C204787440 @default.
• W1569015762 hasConcept C2775847089 @default.
• W1569015762 hasConcept C2776910235 @default.
• W1569015762 hasConcept C2778695967 @default.
• W1569015762 hasConcept C2780471494 @default.
• W1569015762 hasConcept C62520636 @default.
• W1569015762 hasConcept C71924100 @default.
• W1569015762 hasConcept C93391505 @default.
• W1569015762 hasConceptScore W1569015762C121332964 @default.
• W1569015762 hasConceptScore W1569015762C132439834 @default.
• W1569015762 hasConceptScore W1569015762C142724271 @default.
• W1569015762 hasConceptScore W1569015762C147597530 @default.
• W1569015762 hasConceptScore W1569015762C148093993 @default.
• W1569015762 hasConceptScore W1569015762C148898269 @default.
• W1569015762 hasConceptScore W1569015762C155574463 @default.
• W1569015762 hasConceptScore W1569015762C155647269 @default.
• W1569015762 hasConceptScore W1569015762C161790260 @default.
• W1569015762 hasConceptScore W1569015762C178790620 @default.
• W1569015762 hasConceptScore W1569015762C178907741 @default.
• W1569015762 hasConceptScore W1569015762C179104552 @default.
• W1569015762 hasConceptScore W1569015762C185592680 @default.
• W1569015762 hasConceptScore W1569015762C204787440 @default.
• W1569015762 hasConceptScore W1569015762C2775847089 @default.
• W1569015762 hasConceptScore W1569015762C2776910235 @default.
• W1569015762 hasConceptScore W1569015762C2778695967 @default.
• W1569015762 hasConceptScore W1569015762C2780471494 @default.
• W1569015762 hasConceptScore W1569015762C62520636 @default.
• W1569015762 hasConceptScore W1569015762C71924100 @default.
• W1569015762 hasConceptScore W1569015762C93391505 @default.
• W1569015762 hasIssue "16" @default.
• W1569015762 hasLocation W15690157621 @default.
• W1569015762 hasOpenAccess W1569015762 @default.
• W1569015762 hasPrimaryLocation W15690157621 @default.
• W1569015762 hasRelatedWork W2015346171 @default.
• W1569015762 hasRelatedWork W2061733814 @default.
• W1569015762 hasRelatedWork W2082340496 @default.

• next