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- W156905851 abstract "Abstract Ethylene polymerization catalysts based on titanium, vanadium, chromium, and zirconium display dramatic changes when the ligand environment at the active site is altered. Catalysts with a ligand environment involving chloride, alkoxide, electron-donor compounds, alkyl, cyclopentadienyl, or indenyl groups show distinctive polymerization characteristics. These characteristics include polymer molecular weight and molecular weight distribution. Catalyst response parameters such as comonomer incorporation, hydrogen response, and catalytic activity are influenced by ligand environment at the active site. Changes in the level of unsaturation at active metal centers can also have a profound effect on polymerization kinetics and the nature of the final reaction products. Alpha-olefins play a subtle role in altering the structure of the active centers. Copolymerization studies provide a powerful tool for probing the steric and electronic features of olefin polymerization catalysts." @default.
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- W156905851 date "1994-01-01" @default.
- W156905851 modified "2023-09-25" @default.
- W156905851 title "37. Ligand Effects at Transition Metal Centers for Olefin Polymerization" @default.
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- W156905851 doi "https://doi.org/10.1016/s0167-2991(08)63053-0" @default.
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