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- W1569061918 abstract "The reaction of xanthosine 5′-phosphate aminase (xanthosine-5′-phosphate:ammonia ligase (AMP), EC 6.3.4.1) with hydroxylamine, xanthosine 5′-phosphate, and adenosine triphosphate results in the formation of 1 mole each of adenosine 5′-phosphate and a derivative of XMP, presumably 2-hydroxylamino-IMP, per mole of aminase. The derivative is enzyme-bound, but can be released by extraction with trichloracetic acid. The compound is a powerful inhibitor of the aminase. These observations account for the ATP- and XMP-dependent inhibition of XMP aminase by hydroxylamine. The XMP derivative is produced by reaction of hydroxylamine with a catalytic intermediate, adenyl-XMP, the other product being AMP. An inhibitor of the formation of the catalytic intermediate, psicofuranine, also prevents the formation of the derivative." @default.
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- W1569061918 date "1968-11-01" @default.
- W1569061918 modified "2023-10-12" @default.
- W1569061918 title "Mechanism of Hydroxylamine Inhibition of Xanthosine 5′-Phosphate Aminase" @default.
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- W1569061918 doi "https://doi.org/10.1016/s0021-9258(18)91934-4" @default.
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