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- W1569077106 abstract "The system investigated vas H2O-Sodiumdodecylsulfate (NaDS). The solubility of NaDS in H2O (2°–21°C) has been measured by Hutchinson et al1, and the critical micelle concentration (c.m.c.) (10°–55°C) by Goddard and Benson2. Their results are shown in Fig. 1. To complete this “phase diagram”, we have measured the c.m.c. below the Krafft point (8.9 . 10-6 mol cm-3; 282.1 K). For this purpose, solutions up to 16 . 10-6 mol cm-3 NaDS were prepared at room temperature, transferred into a conductivity cell and then cooled down to temperatures as low as 2.5°C. Like Goddard and Benson2 we could represent the results by two straight lines, the intersection of which was taken as the c.m.c. at that temperature. These values are shown in Fig. 1 as full circles. The supercooled solutions were quite stable, and precipitation of the solid phase could only be initiated by adding a few crystals. This indicates that the molecules in the micelles are in a liquid like state, so that the micelles as such do not act as nuclei for the solid phase." @default.
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- W1569077106 date "1975-01-01" @default.
- W1569077106 modified "2023-09-25" @default.
- W1569077106 title "On the Kinetics of the Formation of NaDS Micelles" @default.
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