Matches in SemOpenAlex for { <https://semopenalex.org/work/W1569168599> ?p ?o ?g. }
- W1569168599 endingPage "12900" @default.
- W1569168599 startingPage "12880" @default.
- W1569168599 abstract "Conformations of the crystalline 3,3,3-trifluoro-2-methoxy-2-phenylpropanamide derivatives (MTPA amides) deposited in the Cambridge Structural Database (CSD) were examined statistically as Racid-enantiomers. The majority of dihedral angles (48/58, ca. 83%) of the amide carbonyl groups and the trifluoromethyl groups ranged from -30° to 0° with an average angle θ1 of -13°. The other conformational properties were also clarified: (1) one of the fluorine atoms was antiperiplanar (ap) to the amide carbonyl group, forming a staggered conformation; (2) the MTPA amides prepared from primary amines showed a Z form in amide moieties; (3) in the case of the MTPA amide prepared from a primary amine possessing secondary alkyl groups (i.e., Mosher-type MTPA amide), the dihedral angles between the methine groups and the carbonyl groups were syn and indicative of a moderate conformational flexibility; (4) the phenyl plane was inclined from the O-Cchiral bond of the methoxy moiety with an average dihedral angle θ2 of +21°; (5) the methyl group of the methoxy moiety was ap to the ipso-carbon atom of the phenyl group." @default.
- W1569168599 created "2016-06-24" @default.
- W1569168599 creator A5024167538 @default.
- W1569168599 creator A5068352055 @default.
- W1569168599 creator A5090157738 @default.
- W1569168599 date "2015-07-16" @default.
- W1569168599 modified "2023-10-16" @default.
- W1569168599 title "Characteristic Conformation of Mosher’s Amide Elucidated Using the Cambridge Structural Database" @default.
- W1569168599 cites W1624721956 @default.
- W1569168599 cites W1965061696 @default.
- W1569168599 cites W1967678398 @default.
- W1569168599 cites W1974522787 @default.
- W1569168599 cites W1976182027 @default.
- W1569168599 cites W1979368277 @default.
- W1569168599 cites W1979688020 @default.
- W1569168599 cites W1989217272 @default.
- W1569168599 cites W1991444919 @default.
- W1569168599 cites W1992012369 @default.
- W1569168599 cites W1993098512 @default.
- W1569168599 cites W1996940541 @default.
- W1569168599 cites W2007043920 @default.
- W1569168599 cites W2010778449 @default.
- W1569168599 cites W2010871897 @default.
- W1569168599 cites W2011098331 @default.
- W1569168599 cites W2025449527 @default.
- W1569168599 cites W2026973275 @default.
- W1569168599 cites W2027067085 @default.
- W1569168599 cites W2028908910 @default.
- W1569168599 cites W2030701627 @default.
- W1569168599 cites W2032412981 @default.
- W1569168599 cites W2032727997 @default.
- W1569168599 cites W2043966259 @default.
- W1569168599 cites W2045961932 @default.
- W1569168599 cites W2061397090 @default.
- W1569168599 cites W2066690728 @default.
- W1569168599 cites W2074414823 @default.
- W1569168599 cites W2078297903 @default.
- W1569168599 cites W2083107123 @default.
- W1569168599 cites W2085502786 @default.
- W1569168599 cites W2089223497 @default.
- W1569168599 cites W2107387898 @default.
- W1569168599 cites W2110203240 @default.
- W1569168599 cites W2135404569 @default.
- W1569168599 cites W2146318727 @default.
- W1569168599 cites W2148141870 @default.
- W1569168599 cites W2148624934 @default.
- W1569168599 cites W2170309222 @default.
- W1569168599 cites W2312633862 @default.
- W1569168599 cites W2323943045 @default.
- W1569168599 cites W2328405919 @default.
- W1569168599 cites W2333546337 @default.
- W1569168599 cites W2418906416 @default.
- W1569168599 cites W2516070004 @default.
- W1569168599 cites W2949982010 @default.
- W1569168599 cites W2953085192 @default.
- W1569168599 cites W3149016424 @default.
- W1569168599 cites W4238178252 @default.
- W1569168599 doi "https://doi.org/10.3390/molecules200712880" @default.
- W1569168599 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6332137" @default.
- W1569168599 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26193245" @default.
- W1569168599 hasPublicationYear "2015" @default.
- W1569168599 type Work @default.
- W1569168599 sameAs 1569168599 @default.
- W1569168599 citedByCount "4" @default.
- W1569168599 countsByYear W15691685992017 @default.
- W1569168599 countsByYear W15691685992021 @default.
- W1569168599 crossrefType "journal-article" @default.
- W1569168599 hasAuthorship W1569168599A5024167538 @default.
- W1569168599 hasAuthorship W1569168599A5068352055 @default.
- W1569168599 hasAuthorship W1569168599A5090157738 @default.
- W1569168599 hasBestOaLocation W15691685991 @default.
- W1569168599 hasConcept C112887158 @default.
- W1569168599 hasConcept C115624301 @default.
- W1569168599 hasConcept C131779359 @default.
- W1569168599 hasConcept C155518411 @default.
- W1569168599 hasConcept C155647269 @default.
- W1569168599 hasConcept C178790620 @default.
- W1569168599 hasConcept C185592680 @default.
- W1569168599 hasConcept C2776442012 @default.
- W1569168599 hasConcept C2776568683 @default.
- W1569168599 hasConcept C2778439535 @default.
- W1569168599 hasConcept C2780263894 @default.
- W1569168599 hasConcept C32909587 @default.
- W1569168599 hasConcept C71240020 @default.
- W1569168599 hasConcept C8010536 @default.
- W1569168599 hasConcept C89025888 @default.
- W1569168599 hasConceptScore W1569168599C112887158 @default.
- W1569168599 hasConceptScore W1569168599C115624301 @default.
- W1569168599 hasConceptScore W1569168599C131779359 @default.
- W1569168599 hasConceptScore W1569168599C155518411 @default.
- W1569168599 hasConceptScore W1569168599C155647269 @default.
- W1569168599 hasConceptScore W1569168599C178790620 @default.
- W1569168599 hasConceptScore W1569168599C185592680 @default.
- W1569168599 hasConceptScore W1569168599C2776442012 @default.
- W1569168599 hasConceptScore W1569168599C2776568683 @default.
- W1569168599 hasConceptScore W1569168599C2778439535 @default.
- W1569168599 hasConceptScore W1569168599C2780263894 @default.
- W1569168599 hasConceptScore W1569168599C32909587 @default.