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- W1569194297 abstract "Methyl 2-nitrobenzenesulfenate (5) was formed by controlled potential electrolysis (CPE) of N-(2-nitrophenylthio) amines (morpholine (1), piperidine (2), pyrrolidine (3), thiomorpholine (tetrahydro-4H-1, 4-thiazine) (4)) in methanol at a glassy carbon anode. A yellow powder obtained by the electrolysis of 1 reacted with triethylamine to give 2, 4-bis (o-nitrophenylthio)-5, 6-dihydro-1, 4-oxazine (7). CPE of 1-4 in acetonitrile gave 2, 2'-dinitrodiphenyldisulfide (6). These results suggest that the initial step of anodic oxidation of 1-4 in acetonitrile is an EC process (an electron transfer process followed by a chemical reaction), while that in methanol is an ECE process (an electron transfer process followed by a chemical reaction and then an electron transfer process). Enamine is considered to be one of the intermediates in the anodic oxidation of 1-4 in methanol." @default.
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- W1569194297 date "1983-01-01" @default.
- W1569194297 modified "2023-09-23" @default.
- W1569194297 title "Studies on sulfenamides. VIII. Anodic oxidation of 2-nitrobenzenesulfenamides derived from secondary cyclic amines." @default.
- W1569194297 doi "https://doi.org/10.1248/cpb.31.4530" @default.
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