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- W1569197221 abstract "Abstract The X-ray crystal structures of 1,3-diphenyl-2-methylpropane-1,3-dione and 1,3-diphenyl-2-(4-methoxyphenyl)propane-1,3-dione show them both to adopt cis -diketo (Z,Z) conformations with carbonyl—carbonyl dihedral angles of 89.0(3)° (2-methyl derivative), and 85.5(4)° and 77.7(4)° for the two molecules in the asymmetric unit of the 2-(4-methoxyphenyl) derivative. These are the first acyclic β-diketones with an α-hydrogen to be reported which do not have an enol configuration in the solid state." @default.
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- W1569197221 date "1987-10-01" @default.
- W1569197221 modified "2023-09-23" @default.
- W1569197221 title "β-diketone interactions" @default.
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- W1569197221 doi "https://doi.org/10.1016/0022-2860(87)85073-1" @default.
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