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- W1569215759 abstract "Spectrophotometric studies on the behaviour of coproferrihaem in aqueous solution showed that, in the pH range 6.66–8.04, a dimerization process occurs according to the equation 2 monomer The value of K, the pH-independent dimerization contant, was found to be 2.10 · 10−3, signifying that coproferrihaem shows the least tendency to dimerize of any ferrihaem so far investigated. Forward and reverse rate constants for the dimerization process have been determined by the temperature-jump method. The results suggest that the cation-briding between carboxyl residues, postulated for the dimers of the dicarboxylic ferrihaems, cannot occur between the additional carboxyl residues of coproferrihaem and that the increased negative charge may cause destabilization of the coproferrihaem dimer by repulsion effects." @default.
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- W1569215759 date "1978-12-01" @default.
- W1569215759 modified "2023-09-27" @default.
- W1569215759 title "The dimerization of ferrihaems" @default.
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- W1569215759 doi "https://doi.org/10.1016/0304-4165(78)90108-3" @default.
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