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- W1569220311 abstract "Abstract Dimetalation of 1,4-enynes was carried out with butyllithium in ether at low temperatures. Treatment of the metalated enynes with trimethylsilyl chloride yielded in all cases 1,3-bis(trimethylsilyl)allenes conjugated to a double bond. In one case a bis(trimethylsilyl)-1,3-enyne with one trimethylsilyl group in a vinylic and the other in an allylic position was obtained as an additional product. Enynes not having aryl substituents gave, after short metalation periods and subsequent silylation, a mixture of monosilyl products in addition to the disilyl derivatives." @default.
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- W1569220311 date "1969-08-01" @default.
- W1569220311 modified "2023-09-27" @default.
- W1569220311 title "Metalation reactions" @default.
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- W1569220311 doi "https://doi.org/10.1016/s0022-328x(00)85397-8" @default.
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